UPDATE: Here's a link to another website that hosts the same videos from below and more!

asp.net video tutorial link

Website:
Web Development: http://msdn2.microsoft.com/en-us/asp.net/aa336576.aspx
Beginner Web developer: http://msdn2.microsoft.com/en-us/vstudio/aa700816.aspx

Rating: Highly Recommended

A really descriptive and easily understandable ASP.Net video tutorials that will allow you to quickly start web development. The beginner tutorial is very useful for someone that wants to get started with ASP.Net web development. It uses Screen capture video and is paced decently but get used to pause/play for some. :p

Download: Visual Web Developer 2008 Express edition

The tutorials use Visual Studio Web Developer 2005 version but all the projects should work for 2008 version as well although i haven't confirmed it. All Express edition IDEs are permanently free from Microsoft.

Link to the Microsoft Beginner Developer Learning Center